Going for strain: synthesis of the first 3-imino- azaphosphiridine complexes and their surprising conversion into oxaphosphirane complex valence isomers
نویسندگان
چکیده
a Institut für Anorganische Chemie der Reinischen Friedrich-Wilhelms-Universität Bonn, GerhardDomagk-Str.1, 53121 Bonn, Germany. Fax: +49 228 739616; Tel: +49 228 735345; E-mail: [email protected]. bInstitut for Chemical Research, Kyoto University, Gokasho Uji, Kyoto, 611-0011, Japan. c Departamento de Química Orgánica, Universidad de Murcia,Campus de Espinardo, 30100 – Murcia, Spain. Fax: +34 868 884149; Tel: +34 868 887489; E-mail: [email protected]
منابع مشابه
Synthesis and Evaluation of Antimicrobial Activity of Metal Complexes of 4-(2'-Hydroxy Phenyl Imino) Phenyl Sulphonamide
Keeping in view the promising potential of carbonic anhydrase inhibitor based antimicrobials and enhancement of carbonic anhydrase inhibitory activity by metal complexes of sulfonamides, with an aim to develop better antimicrobial agents we have attempted investigation of antimicrobial activity of metal complexes of 4-(2'-hydroxy phenyl imino) phenyl sulphonamide. Sulfanilamide was taken...
متن کاملTwo new Cu(II) and Zn(II) Schiff base complexes: Synthesis, characterization and their biological activity
New two nano- sized Schiff base complexes [M(L)], where L= 2, 2'-((1E, 1E')-(1, 2 phenylen bis (azanylylidene)) bis (methanylylidene)) bis (4-bromo phenolato) and M=Cu or Zn, (a, b complexes) were synthesized by ultrasonic irradiation. These complexes were characterized by elemental analysis, molar conductivity, FT-IR, fluorescence emission, 1H NMR, field emission scanning electron spectroscopy...
متن کاملTwo new Cu(II) and Zn(II) Schiff base complexes: Synthesis, characterization and their biological activity
New two nano- sized Schiff base complexes [M(L)], where L= 2, 2'-((1E, 1E')-(1, 2 phenylen bis (azanylylidene)) bis (methanylylidene)) bis (4-bromo phenolato) and M=Cu or Zn, (a, b complexes) were synthesized by ultrasonic irradiation. These complexes were characterized by elemental analysis, molar conductivity, FT-IR, fluorescence emission, 1H NMR, field emission scanning electron spectroscopy...
متن کاملSynthesis and DFT calculations of spirooxaphosphirane complexes.
In situ formed Li/Cl phosphinidenoid complexes [Li(12-crown-4)][M(CO)5(ClPC5Me5)] 3a-c (M = Cr, Mo, W) reacted with cyclobutanone (4), cyclopentanone (5) and cyclohexanone (6) in Et2O to yield the first P-C5Me5 substituted C(3)-spirofused oxaphosphirane complexes 7a-c, 8a and 9a,a'. In the case of cyclopentanone and 1a the outcome of the reaction in THF was different: here the formation of 8a a...
متن کاملFirst examples of oxaphosphirane pentacarbonylchromium(0) and -molybdenum(0) complexes: synthesis, structures and reactions.
Synthesis of the first oxaphosphirane chromium(0) and molybdenum(0) complexes of the type [{(R(1)PCH(R(2))-O}M(CO)(5)] (R(1) = C(5)Me(5)) (8a-e, 15a-e) and (R(1) = CH(SiMe(3))(2)) (9a-e, 16a-e) via reaction of dichloro(organo)- (1, 2, 10, 11) and chloro(organo)phosphane complexes (3,4,12) with lithium bases and aldehydes 7a-e is reported. Furthermore, bicyclic 1,3-oxaphospholane complexes 17 an...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2014